Rubottom oxidation - Wikipedia
The Rubottom oxidation is a useful, high-yielding chemical reaction between silyl enol ethers and peroxyacids to give the corresponding α-hydroxy carbonyl product. [ 1 ] [ 2 ] [ 3 ] [ 4 ] [ 5 ] The …
Rubottom Oxidation - Organic Chemistry Portal
Rubottom Oxidation. The synthesis of α-hydroxy ketones is achieved by reaction of silyl enol ethers with mCPBA, with subsequent rearrangement. Aqueous work up or reaction with TBAF …
ルボトム酸化 - Wikipedia
ルボトム酸化（ルボトムさんか、Rubottom oxidation）とは有機化学における人名反応のひとつで、シリルエノールエーテル（下式左）がメタクロロ過安息香酸 (mCPBA) と反応して α-シ …
Rubottom Oxidation - an overview | ScienceDirect Topics
The oxidation of silyl enol ethers with MCPBA, known as the Rubottom oxidation, is an important method for the regioselective formation of α-hydroxyketones. Recent research in this area has …
ルボトム酸化 Rubottom Oxidation - Chem-Station (ケムステ)
デーヴィス酸化 Davis Oxidation; プリリツェフ エポキシ化 Prilezhaev Epoxidation; 三枝・伊藤酸化 Saegusa-Ito Oxidation . 関連書籍 . 外部リンク. Oxidation (A.Myers’ Lab.: PDF) Rubottom …
鲁伯特姆氧化反应（Rubottom Oxidation） - 化学空间 Chem ...
2014年9月1日 · 概要; 硅烯醇醚在mcpba或二环氧乙烷中被环氧化后，能够快速进行重排，得到α-硅氧基酮。该反应经常被用于在α位选择性导入 ...
Rubottom酸化はカルボニルのα位に酸素原子を導入する酸化法
今回は、シリルエノールエーテルからα-シリルオキシケトンを合成できるRubottom oxidation（ルボトム酸化）について考えたいと思います。 電子豊富なシリルエノールエー …
Rubottom Oxidation - Major Reference Works - Wiley Online Library
2010年9月15日 · The transformation of a ketone into the corresponding α-hydroxyketone by means of the epoxidation or dihydroxylation of a silyl enolate of the ketone with m …
Rubottom Oxidation | Thermo Fisher Scientific - US
Today, the peroxyacid oxidation of silyl enol ether substrates to prepare the corresponding alpha-hydroxy carbonyl compounds is known as the Rubottom oxidation. Synthesis of the potent anti …
Rubottom Oxidation - Chem-Station Int. Ed.
2015年10月6日 · Rubottom Oxidation (organic-chemistry.org) Rubottom Oxidation (Wikipedia) alpha-hydroxylation, oxidation of silyl enol ethers. Oxidation with Dioxiranes Marshall …
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